منابع مشابه
Alkaline Hydrolysis of N-acetylolycine
A faster reaction of the cation is expected for the compounds with a free amino group in the acyl moiety. Such an increase was observed for Ala-Ala-pnitroan~lide b.ut not with Ala-p-nitroanilide. Fischer · et al. concluded that a larger inc-rease in k1 with the latter compound was compensated by a reductionin k2/ki. so that the observed k1k2/(k~1 + k2) term remains the same. This assumption of ...
متن کاملUltra - violet absorption cross sections of isotopically substituted nitrous oxide species : 14 N 14 NO , 15 N 14 NO , 14 N 15 NO and 15 N 15 NO
The isotopically substituted nitrous oxide species 14N14NO, 15N14NO, 14N15NO and 15N15NO were investigated by ultra-violet (UV) absorption spectroscopy. High precision cross sections were obtained for the wavelength range 181 to 218 nm at temperatures of 233 and 283 K. These data are used to calculate photolytic isotopic fractionation constants as a function of wavelength. The fractionation con...
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The paper assesses the marginal welfare and equity impacts of three transport instruments in the presence of three transport externalities: congestion, air pollution and accidents. It considers a second-best economy in which the government has to use distortionary taxes for revenue-raising and distributional purposes. The assessment uses an applied general equilibrium model for Belgium. The tra...
متن کاملEnzymatic hydrolysis of N-substituted aminoacyl-tRNA.
The mechanism of the release of polypeptide chains from the ribosome-messenger RNA complex is not fully understood. It has been reported that free polypeptide chains are formed in cell-free protein-synthesizing systems, directed by polyribonucleotides, only if these polynucleotides contain statistically high frequencies of UAA codons.'-5 However, we do not know how the chain is released from th...
متن کاملFractionation of 14 N 15 N 16 O and 15 N 14 N 16 O During Photolysis at 213 nm
Motivated by Yung and Miller’s suggestion [1997] that N2O is isotopically fractionated during UV photolysis in the stratosphere, we have studied the photolysis rates of the NNO and NNO structural isotopomers. In this study, we follow the concentrations of these compounds with FTIR spectroscopy during photolysis at 213 nm. Our results show that, as Yung and Miller predicted, the photolysis rate ...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1955
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.58.34